Whenever heat energy is given liquids are also going to
expand like solids. The force of attraction between the liquid molecules is bit
less when compared with the solids and hence expansion is going to be more in
the case of the liquids. Solids have a specific shape and hence they have
linear expansion, areal expansion and volume expansion. Liquids don’t possess
any particular shape and they acquire the shape with respect to the container.
As a result liquids have no linear and areal expansions and we can study the
expansion of the liquid is only through volume expansion.
Solids have an advantage that we can supply the heat energy
directly to them. But liquids have to be taken in a container and then heat
energy has to be supplied to the container. First the heat energy is absorbed
by the container and it expands. After receiving sufficient energy it will
further pass it to the liquids and the liquid starts expanding.
At the initial stage when the solid is expanding it appears
like the liquid level is falling down. It is because of volume expansion of the
solid container. Therefore liquids have two types of expansion coefficients.
One is the apparent expansion coefficient and the other one is the real
expansion coefficient. Apparent expansion coefficient of a liquid depends not
only on the nature of the liquid but also on the nature of the container.
Real expansion coefficient of the liquid depends only on the
nature of the liquid but never on the container of the liquid.
Relation between coefficients of apparent expansion and real
expansion
1.Consider a liquid in a long necked vessel as shown below.
Let the liquid is filled up to a level A in the solid container.
2.When heat energy is supplied as the container expands the
liquid level falls below the given level to B. A human eye cannot identify it
because its value is small.
3.When the heat energy is further supplied the liquid level
rises from the lower level B.
4.Though it appears like liquids is raising from A, it is
actually raising from B. The expansion appears for as from A to C and it is
called apparent expansion.
5.Expansion of liquid really happens from B to C and it is
called real expansion.
6.The real expansion of the liquid is equal to the sum of
apparent expansion of the liquid and the volume expansion of the solid
container.
Coefficient of apparent expansion of the liquid is defined as
the ratio of apparent change in the volume of the liquid to its original volume
per 1°C rise in temperature.
Coefficient of real expansion of the liquid is defined as the
ratio of real change in the volume to its original volume per 1°C rise in
temperature.
Problem:
A liquid is taken into different containers having
different coefficients of linear expansions. The apparent expansion coefficient
in one of the container is given then what is the apparent coefficient of
expansion when the liquid is in the second container?
The concept behind the problem means coefficient of real
expansion of a liquid depends only on the nature of the liquid .As the liquid
is same, even though the containers are different it is going to have the same
coefficient of real expansion. Basing on this concept the problem is solved in
the above-mentioned diagram.
Problem and solution
A glass vessel of 1 liter volume how much of the mercury has
to be filled so that the level of the mercury remains constant at all
temperatures? Assume that volume expansion coefficient of mercury is a seven
times the volume expansion coefficient of glass.
In solving the problem we have to apply a simple concept. If
the level of the mercury has to remain constant at all temperatures, increase
in the volume of the mercury shall be equal to the increase in the volume of
the glass vessel.
To measure the apparent expansion coefficient of a liquid we
have a small formula. It is the ratio of mass of the liquid expelled to the
mass remaining per unit rise in temperature.
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